Volume 490
Main Index

Issues 1-2, Pages 1-254 (22 March 1995)

Editorial Board Page iii

Synthesis and crystal structure of the organogermanium complex of ytterbium [(Ph2Ge)4Yb(THF)4]·4THF with a five-membered Ge4Yb cycle Pages C29-C31 Leonid N. Bochkarev, Valentin M. Makarov, Lev N. Zakharov, Georgy K. Fukin, Alexander I. Yanovsky, Yuri T. Struchkov

Untersuchungen von polymerisations- und metathesereaktionen, XXII. Darstellung und katalytische reaktionen von substituierten titanocendichloriden Pages C32-C36 Heinrich lang, Sabine Blau, Andreas Muth, Karin Weiss, Ute Neugebauer

The cobaloximes trans-bis(dimethylglyoxime)(R) CoIII, R = n-C14H29 or n-C15H31. Surprising ambiphilic nature observed in the molecular packing of the longest n-alkyl organometallic compound to be structurally characterized Pages C20-C22 Earl J. Starr, Susan A. Bourne, Mino R. Caira, John R. Moss

Subject index of volume 490 Pages C43-C50

Author index of volume 490 Pages C41-C42

Iron compounds in organic synthesis : A.J. Pearson, Academic press, London 1994, £35 ISBN 3-540-93681-5 Page C37 R. M. G. Roberts

[2 + 2] Dimerization of norbornadiene and its derivatives in the presence of nickel complexes and zinc metal Pages C1-C7 Daw-Jen Huang, Chien-Hong Cheng

Oxidation reactions using water, hydrogen peroxide and halogens to give pallad(IV) cyclopentane complexes PdX(C4H8 {(pz)3BH} (X = OH, Cl, Br, I). The crystal structure of the hydroxoplatinum(IV) complex Pt(OH)Me2{(pz)3BH}, formed by use of water as an oxidant Pages C18-C19 Allan J. Canty, Steven D. Fritsche, Hong Jin, Brian W. Skelton, Allan H. White

Corrigendum to the paper “determination of teh activation parameters of permanent allylic rearrangement in allyl- and methallylboranes and in 1,1-bis(dipropylborylmethyl) ethylene by dynamic NMR spectroscopy” Page C40

Organometallics in synthesis: A manual : M. Schlosser (ed.), Wiley, Chichester, 1994, ix+603 pages £60.00 ISBN 0-471-93637-5 Page C38 Colin Eaborn

The chemistry of the copper and zinc triads : A.J. Welch and S.K. Chapman (eds.) Royal Society of Chemistry, Cambridge, 1993, 260 pages £47.50 ISBN 0-85186-715-4 Page C37 Colin Eaborn

The vinylation of aryl iodides catalysed by Co, Rh and Ir complexes Pages C27-C28 Suresh Iyer

The first example of α-organoseleno arsonium ylides and its Wittig-type reaction Pages C23-C26 Zhi-Zhen Huang, Xian Huang, Yao-Zeng Huang

Catalytic asymmetric synthesis : I. Ojima (ed.), VCH, Weinheim, 1994, 476 pages DM186.00 £76.00 ISBN 3-527-89532-9 Pages C38-C39 S. Caddick

Une méthode simple et efficace de préparation des dihydrures organotanniques Pages C14-C17 H. Deleuze, B. Maillard

American chemical society advances in chemistry series vol. 238 photosensitive metal-organic systems—mechanistic principles and applications : Charles Kutal and Nick Serpone (eds.) American Chemical Society 1993 pp. xiii+449. $109.95 ISBN 0-8412-2527-3 Page C39 M. Poliakoff

Synthesis and crystal structures of (C8h8)Nd(C5H9C5H4) (THF)2 and [(C8H8)Gd(C5H9C4H4(THF)][(C8H8)GD(C5H9C5H4(THF)2] Pages C8-C13 Jizhu Jin, Xiuli Zhuang, Zhongsheng Jin, Wenqi Chen

The coordinatively unsaturated cluster cations [Pt3{M(CO)3}(μ-Ph2PCH2PPh2)3]+ (M = Re, Mn) Pages 1-6 Jianliang Xiao, Eva Kristof, Jagadese J. Vittal, Richard J. Puddephatt

Reactivity of niobocene dihalogenides toward nitroso derivatives. EPR and IR characterization of the first niobium(IV) complexes containing an ArNO-N,O ligand Pages 7-10 D. Lucas, Y. Mugnier, A. Antiñolo, A. Otero, S. Garcia-Yuste, M. Fajardo

Synthesis of Re-Ru heterobimetallic polyhydride complexes. Study of the influence of ligands bonded to the monometallic precursors on the nature of the isolated binuclear complexes Pages 11-19 Isabel Moldes, Sergeï Nefedov, Noël Lugan, René Mathieu

Synthesis of 2-(diphenylphosphino)phenolato and 2-(diphenylphosphinomethyl)-4-methylphenolato complexes of titanium and zirconium. X-ray characterization of [(η5-C5H5)2ZrCl(OC6H4PPh2] and [(η5-C5H5)2 Zr(OC6H4PPh2)2] Pages 21-28 Laurent Miguel, Mario Basso-Bert, Robert Choukroun, Rachid Madhouni, Bettina Eichhorn, Michel Sanchez, Marie-Rose Mazières, Joël Jaud

Chemical bonding in metalaheterocumulene complexes: II Demonstration of a temperature dependant conformational disorder of the methyl groups in [(CO)5CrNCN(C2H5)2] Pages 29-34 Marie-Noëlle Ohnet, Anne Spasojevic-de Biré, Nguyen Quy Dao, Peter Schweiss, Jean-Michel Kiat, Pierre Gregoire, Helmut Fischer, David Reindl

Metal complexes of biologically important ligands: Synthesis of amino acidato complexes of PdII containing a C,N-cyclometallated group as an ancillary ligand Pages 35-43 R. Navarro, J. García, E. P. Urriolabeitia, C. Cativiela, M. D. Diaz-de-Villegas

Multinuclear magnetic resonance studies on intramolecular chalcogen-tin coordination in compounds of the type Me2Sn(X)CH2CH2P(E)Ph2 (X = Halogen, E = Chalcogen) Pages 45-49 T. N. Mitchell, B. Godry

Bis(di-t-butylphosphino)methane complexes of rhodium: homogeneous alkyne hydrosilylation by catalyst-dependent alkyne insertion into Rh---Si or Rh---H bonds. Molecular structures of the dimer [(dtbpm)RhCl]2 and of the silyl complex (dtbpm) Rh[Si(OEt)3](PMe3) Pages 51-70 Peter Hofmann, Claudia Meier, Wolfgang Hiller, Maximilian Heckel, Jürgen Riede, Martin U. Schmidt

Reaction of an iron-lithium complex with tolane and the structure of dilithiumtetraphenylbutadiene formed Pages 71-73 T. A. Bazhenova, A. F. Shestakov, A. E. Shilov, M. Yu. Antipin, K. A. Lyssenko, Yu. T. Struchkov

Nucleophile-assisted racemisations of halosilanes — kinetic studies Pages 75-82 Alan R. Bassindale, Juliana C. -Y. Lau, Peter G. Taylor

M(CO)4 (M = Mo or W) complexes of 2,6-bis(methylthiomethyl)pyridine (L1) and 2,6-bis(p-tolylthiomethyl)pyridine (L2): a dynamic NMR study Pages 83-88 Edward W. Abel, Elizabeth S. Blackwall, Michel L. Creber, Peter J. Heard, Keith G. Orrell

Syntheses and properties of cyanamide and cyanoguanidine complexes of platinum(II). X-Ray structure of trans-[Pt(CF3)(NCNEt2)(PPh3)2][BF4] Pages 89-99 M. Fátima C. Guedes da Silva, Elsa M. P. R. P. Branco, Yu Wang, João J. R. Fraústo da Silva, Armando J. L. Pombeiro, Roberta Bertani, Rino A. Michelin, Mirto Mozzon, Franco Benetollo, Gabriella Bombieri

Complexation and aromatization of α,β-unsaturated cyclic ketones by Ru(H2O)62+ and (Bz)Ru(H2O)32+: molecular structure of (η6-Tosylate)(η5-hydroxycyclopentadienyl)Ru and of (η6-Tosylate)(η6-1,4-dihydroxy-2,3,5,6-tetramethylbenzene)Ru Pages 101-109 U. Koelle, Chr. Weißschädel, U. Englert

The reaction of tetrahydridododecacarbonyltetrarhenium(0) with pyridine and some nitrogen-containing bases Pages 111-116 Sen Ren Wang, Cheu Pyeng Cheng

Insertion reaction of isocyanide into the Pt---C bonds of 2,5-thienylene-bridged diplatinum complexes and 2-thienyl platinum complexes: molecular structure of Cl(Et3P)2PtC(=NC6H4OMe-p)C4H2SC (=NC6H4OMe-p)Pt(PEt3)2Cl·CH2Cl2 Pages 117-123 Kiyotaka Onitsuka, Kazuyoshi Murakami, Kenji Matsukawa, Kenkichi Sonogashira, Tomohiro Adachi, Toshikatsu Yoshida

Photochemische reaktionen von übergangsmetall-organyl-komplexen mit olefinen XI. Photochemisch induzierte C---C-verknüpfung von tricarbonyl-η5-2,4-dimethyl-2,4-pentadien-1-yl-mangan mit 1-dimethylamino-2-propin—Synthese eines η5-7-dimethylamino-N-2,4-heptadien-1-yl-chelatkomplexes, Pages 125-131 Cornelius G. Kreiter, Ernst-Christian Koch, Walter Frank, Guido J. Reiß

Photochemische reaktionen von übergangsmetall-organyl-komplexen mit Olefinen XII. Photochemisch induzierte [5 + 2, 3 + 2]-cycloadditionen von alkinen an tricarbonyl-η5-cyclohexadienly-mangan Pages 133-141 Cornelius G. Kreiter, Christian Fiedler, Walter Frank, Guido J. Reiβ

Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors Pages 143-148 Paul D. Beer, Christopher G. Crane, Jonathan P. Danks, Philip A. Gale, Jerome F. McAleer

Homoleptic carbene complexes VI. Bis{1,1′-methylene-3,3′-dialkyl-diimidazolin-2,2′-diylidene}palladium chelate complexes by the free carbene route Pages 149-153 Wolf Peter Fehlhammer, Thomas Bliss, Ulrich Kernbach, Irene Brüdgam

Tri-, penta-, and hexa-phospha ruthenocenes Pages 155-162 Peter B. Hitchcock, John F. Nixon, Robson M. Matos

(Z)-1-[2-(Triarylstannyl)vinyl]-1-cycloheptanols: Synthesis, characterization, halodemetallation and crystal structures Pages 163-171 Fangzin Fu, Hongyu Li, Dongsheng Zhu, Qunxin Fang, Huade Pan, Edward R. T. Tiekink, François Kayser, Monique Biesemans, Ingrid Verbruggen, Rudolph Willem, Marcel Gielen

Synthesis and characterisation of the methylene-inserted mixed-chalcogenide compounds Fe2(CO)6(μ-SeCH2Te) and Fe2(CO)6(μ-SCH2Te) Pages 173-178 Pradeep Mathur, Bala. Manimaran, Md. Munkir Hossain, Rupa Shanbag, Jayshree Murthy, Iyer S. Saranathan, C. V. V. Satyanarayana, Mohan M. Bhadbhade

Synthesis of novel platinum-silver and platinum-copper complexes with bridging alkynyl ligands Pages 179-188 J. Forniés, E. Lalinde, A. Martín, M. T. Moreno

Reactions of nickelocene with methyl-, ethyl- and vinyl-lithium compounds. Hydrogen elimination and cyclopentadienyl ring hydrogenation Pages 189-195 S. Pasynkiewicz, W. Buchowicz, J. Popawska, A. Pietrzykowski, J. Zachara

Novel rearrangements of fused zwitterionic heterocyclic systems Pages 197-202 Bernd Wrackmeyer, Susanna Kerschl, Heide E. Maisel, Wolgang Milius

Photochemical reaction of W(CO)6 with SnCl4 II. Synthesis and X-ray structure of tetrachlorobis(triphenylphosphine oxide)tungsten(IV), [WCl4(OPPh3)2] Pages 203-207 Teresa Szymaánska-Buzar, Tadeusz Glwiak

Synthesis of mixed organotin compounds via dialkylstannyl derivatives of sulphomaleic anhydride Pages 209-212 V. I. Shcherbakov, I. P. Malysheva, R. P. Zakharova

Zur Komplexierung von enantiomerenreinen cis- und trans-3-Diphenylphosphino-4-hydroxy-tetrahydrofuranen mit [Rh(COD)2]BF4 Pages 213-219 Armin Börner, Achim Kless, Jens Holz, Wolfgang Baumann, Annegret Tillack, Renat Kadyrov

Addition von Phosphanen an das Cα-Atom von allenyliden(pentacarbonyl)chrom und umlagerung in phosphan-komplexe Pages 221-227 Helmut Fischer, David Reindl, Carsten Troll, Frédéric Leroux

Hydrazinocarben-Metallkomplexe—synthese aus allenylidenkomplexen und hydrazinen, umlagerung und cyclisierung Pages 229-237 Helmut Fischer, Gerhard Roth

Cyclopropanation and epoxidation of 1,2-distannylalkenes and 1-silyl-2-stannylalkenes Pages 239-242 T. N. Mitchell, B. Kowall

Crystal structures of anil of benzoylferrocene and its derivative of mercury: Specific arrangement of the ferrocenyl and phenyl groups around the C=N bond Pages 243-247 Shou Quan Huo, Ying Zhu, Yang Jie Wu

13C NMR spectra of cyclomercurated ferrocenylimines: Substituent effects and conformations in the ferrocenes Pages 249-254 Yang Jie Wu, Shou Quan Huo, Li Yang, Chen Xia Du